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A leading university in France is offering a PhD position in Chemistry focused on exploring innovative extraction processes. The candidate will investigate rheological properties and phase separation, requiring a Master’s degree in physics, chemistry, or chemical engineering. The contract is full-time for 36 months with a gross salary of 2,669 EUR monthly, located on the Grenoble campus.
Organisation/Company Universite Grenoble Alpes Department PhD@Tec21 Research Field Chemistry » Physical chemistry Researcher Profile First Stage Researcher (R1) Positions PhD Positions Country France Application Deadline 28 Feb 2026 - 13:00 (Europe/Paris) Type of Contract Temporary Job Status Full-time Offer Starting Date 1 Oct 2026 Is the job funded through the EU Research Framework Programme? Horizon Europe – COFUND Marie Curie Grant Agreement Number 101217261 Is the Job related to staff position within a Research Infrastructure? No
Context
Recycling and depolluting are some of the biggest tasks of our society in the current time. For this purpose, finding greener processes for ionic or molecular extraction, based on liquid-liquid phase separation, is one of the very challenging problems faced to material scientists. In this aim, thermomorphic Aqueous Biphasic Systems (ABS) have been explored and concept has been proved. Beyond this nowadays established extraction process, further properties of the solutions, at equilibrium or under external constraints, can be explored to optimize the extraction paths.
In this context, the objective of this project is to explore a system based on decanoic acid and lidocaine, a deep eutectic solvent avoiding the use of strong (HCl, HNO3…) acids, still enabling extraction of organic pollutants or nickel ions. It presents rich organization properties at the nanometric scale, even leading to anisotropic phases, and viscosities spanning several orders of magnitude between the different liquid phases. Regarding extraction processes, rheological properties play an important role in terms of transport of pollutants from one phase to another, flow velocity during mixing, separation kinetics etc.
Understanding the relation between rheological properties and phase separation, as well as rheology and transport in the bulk solution and across the liquid-liquid interface is the first aim of this project. Furthermore, the anisotropic organisation, at the molecular level, of the solution, may have consequences in terms of impurities locations and transport. We therefore aim at understanding the implications of this anisotropy on the extraction process. Eventually, a shear flow will reinforce this anisotropy and may be a new way of improving these processes in such self-organized liquid systems.
The PhD will be carried on between two laboratories located on the Grenoble campus:
The PhD will be carried out under the direction of Marie Plazanet (LIPhy) and Frédéric Pignon (LRP). Isabelle Billard (LEPMI, Grenoble), as collaborator, is also part of the team.
Mission and main activities
The objective of this project is to explore the system based on decanoic acid and lidocaine. This particular system combines the properties of aqueous, thermomorphic systems and deep eutectic solvents. It presents rich organization properties at the nanometric scale because of dimers formations and organisation, even leading to anisotropic phases, and viscosities spanning several orders of magnitude between the different liquid phases.
We will first investigate the aqueous biphasic properties for extraction processes. Here, rheological properties play an important role in terms of transport of pollutants from one phase to another, flow velocity during mixing, phase separation kinetics etc. Understanding, at different scales, the relation between rheological properties and phase separation, as well as rheology and transport in the bulk solution and across the liquid-liquid interface is the first aim of this project.
Furthermore, the anisotropic organization, at the molecular level, of the solution, may have consequences in terms of impurities locations and transport. This can be explored either in monophasic or biphasic states. We therefore aim at understanding the implications of this anisotropy on the extraction process. Eventually, a shear flow will reinforce this anisotropy and may be a new way of improving these processes in such self-organized liquid systems.
The proposed work is split into three axes. The first one is centered on a deeper characterization of the system at equilibrium. The second one aims at giving a microscopic description of the origins of the flow properties, using structural characterizations (small-angle X-ray and light scattering dichroism) under shear flow. Eventually, the third package will investigate the transport properties, in characterizing diffusion processes in the different phases or shear/flow conditions in order evaluate the effect on the extraction efficiencies and kinetics.
Following a first work of characterizations across the phase diagram, different axis could be taken. Possible research axes:
The ideal candidate should hold a Master’s degree (or equivalent) in physics, chemistry or chemical engineering, with a strong background in one or more of the following fields: liquid-liquid extraction, scattering techniques (light, X-ray or neutrons), rheology, characterization techniques for soft matter.
Disciplinary skills, experience
Strong experimental and analytical skills, interests in interdisciplinary research are essential.
Personal skills
The project requires good organizational, time management abilities and strong communication skills to collaborate with different research teams. Candidate’s key assets for success in this project are strong scientific curiosity together with a proactive attitude, perseverance, and openness to learning new methods. The candidate should be capable of working independently and creatively, with excellent analytical and problem-solving skills and a high precision in experimentation and reporting.
Languages ENGLISH Level Excellent
Université Grenoble Alpes (UGA) is offering a 36-month full-time work contract. In line with the European Commission rules for Marie Skłodowska‑Curie grant holders, the remuneration will consist of a gross monthly salary of 2,669 EUR. The estimated net salary to be perceived by the PhD fellow will be between 2,050 and 2,152 EUR.
Benefits include:
The programme is open to applicants of all nationalities. To be eligible, applicants must meet all of the following conditions:
This recruitment takes place within the PhD@Tec21 Programme, which is co‑funded as part of the Marie Skłodowska‑Curie COFUND actions under the grant agreement #101217261. The recruitment process follows a specific selection and evaluation procedure with particular eligibility criteria, all of which are detailed in the applicant guide available on PhD@Tec21 Website
Applications sent by email will not be considered. Please submit your application exclusively through the online portal, which can be accessed via the PhD@Tec21 Webs